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In his Autobiography, Charles Willson Peale recorded painting Dr. Williams and his wife in Accomack County. The location and subject are unknown.
Reference: “During the stay of Peale in Accomack he painted the portraits of Doctr. Williams & Lady,” in Peale’s Autobiography
See: Peale’s Autobiography, in Lillian Miller, ed., Selected Papers of Charles Willson Peale and his Family, V (1983): 25.